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In this research, four binuclear complexes:[(phen)Cd(NO3)2(μ-phen-dion)Cr(NO3)2(phen)] (NO3)2, [Cr(4-Ptpy)(μ-phen-dion)](NO3)[Cd(4-Ptpy)(μ-phen-dion)](NO3),[Cr(4-Ptpy)(μ-phen-dion)] (NO3)Cr(4-Ptpy)(μ-phen-dion)](NO3), and [Cd(4-Ptpy)(μ-phen-dion)](NO3) [Cd(4-Ptpy)(μ-phen-dion)] (NO3) were synthesized using reaction of chromium(III) nitrate nonahydrate, cadmium (II) nitrate tetrahydrate, phendion, and 4-phenylterepyrydine. The complexes were characterized using FT-IR spectroscopy, UV-Vis spectroscopy, 1H NMR, elemental analysis, and cyclic voltammetery (CV). These complexes were found to be binuclear coordination complexes. The chromium and cadmium centers were achieved hexacoordination by coordinating with 4-phenylterepyrydine groups, as tridentate chelating ligands and phendion as bidentate chelating ligands. keywords: Binuclear complex, Phendion, chromium, Cadmium, and terpyrydine.

Synthesis and Characterization of new Binuclear Chromium, Cadmium Complexes based on Terpyridine and Phenanthroline