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Palladium(II) and platinum(II) complexes containing the mixed ligands tertiary diphosphinesdppm. dppp and dppf with Thioester ligand S-1H benzo[d] imidazole-2-yl benzothioate (HSBIBT) have been prepared by the reaction of PdCl2 and PtCl2 with one equiv of tertiary diphosphines ligands to form [Pd(k-dppf)Cl2], [Pd(k -dppp)Cl2] and [Pt(k -dppmCl)Cl2] complexes and then add the ligand HSBIBT to these complexes to form mixed ligand complexes. The prepared complexes have been characterized by single-crystal X-ray diffraction, elemental analysis, magnetic susceptibility, molar conductance, IR spectral data and UV-Visible. The results suggested that the ligand HSBIBT bonded to the metal through N atom and square planner geometries were assigned for the complexes.

Mixed Ligand, Palladium(II) and Platinum(II) Complexes of Tertiary DiphosphineswithS-1H Benzo[d] Imidazole-2-yl Benzothioate