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A mononuclear complex of [Zn(tta)2(H2O)2]-(3)-(tta = deprotonated of 1-thenoyl-4,4,4trifluoro acetone-(1)-has been prepared by the reaction of 1-thenoyl-4,4,4-trifluoro acetone (H-tta: 1) with Zn(OAc)2.4H2O (OAc = O2CMe) in a 2:1 molar ratio complex 3 can be extended to form a coordination polymers of general formula [Zn(tta)2(X)]n (X = 4,4'-bipy (4), pz (5) by the reaction of zinc atom in 3 with s-donor ligand such as 4,4-bipyridine (4,4'-bipy) and pyrazin (pz). The reaction completion was controlled via FTIR and elemental analysis.

Synthesis and Characterization of Zinc β-Diketonate Complex Extended to the Macromolecular Polymers