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Poly(o-anisidine)–Poly(ethylene terephthalate) composite film was prepared by chemical oxidative polymerization method. The composite film shows a conductivity of about 15.6 K Ω−1 cm−1 with 3.5 wt. % of POA. Fourier Transform infra-red (FT-IR) and UV–vis spectral analyses reveal the existence of hydrogen bonding interactions between the groups in PET and POA. X-Ray diffraction analysis informs that the amorphous characteristic of PET is affected by the presence of POA in the composite. UV–vis spectral results demonstrate that there exists cross-linking in the composite film when the POA in the composite undergoes doping and dedoping. AFM micrographs confirm the formation of genuine composite between POA and PET.

Microstructure and Thermal Behavior of Poly(o-anisidine)/Poly(ethylene terephthalate) Composite