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. In the studies normally carried out so for, both the solid reactants do not have any impurities. The main motivation of the earlier work, including that of the senior author (R.A.) in this field was to obtain a better understanding of the reaction mechanism of solid-solid reactions. eg 2,5 ABSTRACT We discuss the formation of new products in a solid - solid reaction in the capillary as in well as in bulk in the presence of an organic solvent impurity in a small amount. Three reactions namely KI + HgCl 2 , CuI + HgCl 2 and AgI + HgCl 2 were studied. It was found for some of the organic solvent impurities, a small amount of some substance appeared in the half occupied by HgCl 2 . Thus it became clear that some of the organic substances were reacting with HgCl2 to produce a new substance which be an organo-metallic product. In this light HgCl 2 was made to react with the different solvents. However, the new product could be separated out only in two cases, with Cyclohexanone and Dimethylsulfoxide. A black coloured product was formed with Cyclohexanone and with Dimethylsulfoxide the new product was of a light greenish colour. With the other solvents like Acetophenone and Nitrobenzene, the product, if formed, could not be separated out. So a preliminary study of the two products naming these as product A and product B formed with Cyclohexanone and Dimethylsulfoxide respectively has been done. The product A is formed by the reaction of Cyclohexanone solvent with HgCl 2 and product B is formed by the reaction of Dimethylsulfoxide solvent with HgCl 2 both at 80oC, for 5 hours. The preliminary studies carried out were measurement of molecular weight (by elevation of boiling point method), ionicity, XRD, FTIR etc.

Formation of New Products in a Solid-Solid Reaction in the Presence of Organic Solvent Impurity