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Photoluminescent microporous hybrid films with honeycomb patterns were prepared by Breath Figure method via a straightforward, one-step process by doping complex containing Eu into polystyrene–b–polyacrylic (PS–b–PAA) solution. Several key influencing factors, such as the concentration of the block polymer solution, the relative humidity of the atmosphere and the substrates, were investigated to control micro pore size and tune film surface properties. Meanwhile the optical properties of the obtained micro porous hybrid films were analyzed by the ultraviolet and emission spectra.

Preparation of Photoluminescent Microporous Hybrid Films by Breath Figure Method