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Very peculiar electronic structure and local magnetic moment distribution for fee Fe ultrathin films of 1, 2, 3, and 4 monolayers of thickness, epitaxially grown on Cu(001) substrates and covered with some layers of Cu, are calculated. The lattice constant of the Fe film is assumed to be equal to that of Cu, homogeneously in the whole film. The competition between the surface ferromagnetism and bulk antiferromagnetism results in ferromagnetism of 2-monolayer film, asymmetric solution for 3-monolayer film and antisymmetric solution for 4-monolayer film.

Peculiar Properties of Ultrathin fcc Iron Films Epitaxially Grown on Cu(001)