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Few years ago we reported the results of the intensity analysis for non-aqueous lanthanide nitrate pentahydrate solutions [2]. The hypersensitive transition of unexpected high intensity was observed. It was higher than that observed in lanthanide nitrate melts [3] and anhydrous lanthanide nitrates [4]. The conductivity measurements done at low concentration have shown that the electrolyte was 1:2 [2] and at higher concentration 1:1 [5-7]. They have indicated that there are two nitrate ions involved in the first coordination sphere. The surprisingly high intensity of hypersensitive transition in such system was explained by effect of ligand polarizability mechanism of Mason [8, 9]. The structural aspects of spectroscopic properties of formed solvates were investigated.

acta physica polonica. a

Spectroscopic Properties of [Nd(C3H7NO)(NO3)3(H2O)3]·H2O Single Crystal with Tenfold Oxygen Coordination Nd3+Centre