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CuCr1.65Se4 nanopaxticles crystallize in the monoclinic Cr2Se3-type structure of the space group I2/m. The average crystallite size basing on the line broadening is less than 10 nm. With decrease of the size of grains a change from ferromagnetic to ferrimagnetic order, a lack of the magnetization saturation and a strong spin orbit coupling visible in the large value of the Lande factor g(x) = 2.72 are observed. The change in magnetic order is caused by the change of the crystalline symmetry from the cubic phase to monoclinic one.

Synthesis and Magnetic Properties of CuCr1.65Se_4Nanoparticles

Synthesis and Magnetic Properties of CuCr_1.65Se_{_4}Nanoparticles