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Commercially available poly-(1,4-phenylene sulfide) = PPS with trade names TEDUR and RYTON contain a great amount of Fe(III) (order of 10(20) Fe/gram) as shown by electron spin resonance spectra. The curing of the pure and Fe-doped (0.2% Fe2O3) PPS polymers proves that Fe(III) can be used for improvement of the PPS strength by increasing the polymer cross-linking and a decrease in the polymer crystallinity degree as shown by X-ray diffraction.

The Role of Ferric(III) Oxide in Poly-(1,4-Phenylene Sulphide) Curing. EPR and X-ray Studies