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THE OBJECT OF THIS DISSERTATION IS THE COORDINATION CHEMISTRY OF FEW   SUBTITUED BENZOTRIAZOLES FOWARD CU(II). THE RESEARCH WAS CARRIED OUT THROUGH   THE APPROACH OF THE SUBJECT OF CORROSION INHIBITION OF CU BY BENZOTRIAZOLES.  HAVE BEENPREPARED NEW CU(II) COMPOUNDS. AS LIGUAND HAVE BEEN USED MEBTA,   RBTAH WHERE R: ME, NO2, CL AND BTAOH. PARTICULAR EMPHASIS HAS BEEN PLACED ON   DETERMINING THE INFLUENCE OF SEVERAL SYNTHETIC PARAMETERS (MOLAR RATIO OF THE   REACTANTS, NATURE OF THE SOLVENT, NATURE OF THE LIGANDS ETC) ON THE IDENTITY   OF THE REACTION PRODUCTS. THE NEW COMPLEXES HAVE BEEN STRUCTURALLY   CHARACTERIZED BY SINGLE - CRYSTAL X - RAY CRYSTALLOGRAPHY, AND STUDIED BY IR,  UVIVIS SPECTROSCOPIES, BY THERMAL TECHNIQUE (TG, DTA), VARIABLE - TEMPERATURE  MAGNETOCHEMISTRY AND FAR - JR, RAMAN AND EPR SPECTROSCOPIC METHODS. THE    MONODENTATE COORDINATION OF MEBTA MAY IN PART ACCOUNT FOR THE LACK OF    LONG - TERM CORROSION INHIBITION ON CU BY THIS COMPOUND. RBTAH FORMS  PENTANUCLEAR CLUSTERS. THESE CLUSTER AREGOOD MODELS FOR THE CORROSION  INHIBITION OF COPPER BY BENZOTRIAZOLE AND ITS DERIVATIVES BTUOH MAY IS A  GOOD CORROSION INHIBITIOR.

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ΣΥΜΠΛΟΚΕΣ ΕΝΩΣΕΙΣ ΤΟΥ CU(II) ΜΕ ΒΕΝΖΟΤΡΙΑΖΟΛΙΑ ΩΣ ΥΠΟΚΑΤΑΣΤΑΤΕΣ: ΜΟΝΤΕΛΑ ΤΗΣ ΠΑΡΕΜΠΟΔΙΣΗΣ ΤΗΣ ΔΙΑΒΡΩΣΗΣ ΤΟΥ ΧΑΛΚΟΥ ΑΠΟ ΤΟ ΒΕΝΖΟΤΡΙΑΖΟΛΙΟ ΚΑΙ ΤΑ ΠΑΡΑΓΩΓΑ ΤΟΥ