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In the course of screening anticholinergic agents, tipepidine hibenzoate (Asverin®), a piperidine derivative with a tertiary ammonium nitrogen and a potent antitussive agent (1), was found to have a marked anticholinergic activity (2).

PHARMACOLOGICAL PROPERTIES OF A NEW ANTICHOLINERGIC AGENT, 1, 1-DIMETHYL-5-METHOXY-3-(DITHIEN-2-YLMETHYLENE) PIPERIDINIUM BROMIDE (SA-504)