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Vapor-liquid equilibria for the HC1-H2O, HCl-H2O-MgCl2 and HCl-H2O-CaCl2 systems were measured under atmospheric pressure. A new method is proposed to correlate the salt effect on vapor-liquid equilibrium for the volatile strong electrolyte-water system, and a comparison between experimental and calculated results is made for the HCl-H2O-salt and HNO3-H2O-salt systems. The new method is confirmed to be useful for correlating the salt effect on aqueous electrolyte solutions.

Salt effects on vapor-liquid equilibria for volatile strong electrolyte-water systems.