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Alkynes react with commercially available Co2 (CO)8 to give the corresponding alkyne-Co2 (CO)6 complexes. Similarly, treatment of arenes with Cr(CO)6 produces arene-Cr (CO)3 complexes. By taking advantage of the intriguing properties of these metal carbonyl complexes, we developed some selective reactions. In this review, the following topics are discussed: (i) development of selective reactions based on alkyne-Co2 (CO)6 complexes; (ii) development of selective reactions based on arene-Cr (CO)3 complexes; and (iii) their application to syntheses of bioactive compounds.

Development of Highly Selective Reactions Based on Metal Carbonyls and Its Application to Synthesis of Bioactive Compounds