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We examined In(OTf)3-catalyzed enolization and intramolecular Alder-Rickert reactions of cyclohexenone derivatives. The 3-aryl substituted cyclohexenone derivatives bearing an ethoxycarbonyl-substituted alkyne moiety could be converted into the corresponding phenols in comparatively good yield.

chemical and pharmaceutical bulletin/chemical and pharmaceutical bulletin

One-Pot Synthesis of Phenol Derivatives by the Novel Intramolecular Alder–Rickert Reaction: Effects of Aryl Substituent at the 3-Position of Cyclohexenone Derivatives on Reactivity