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Three types of glycoclusters related to an amphoteric glycosphingolipid found in the earthworm Pheretima hilgendorfi were synthesized. The glycoclusters were prepared from a common precursor and a simple approach for the rational design of a glycocluster was developed.

Syntheses of Glycoclusters Containing a Phosphocholine Residue Related to a Glycosphingolipid from the Earthworm Pheretima hilgendorfi