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Pd(0)-catalyzed intramolecular cyclic reaction via a pi-allylpalladium complex provided an indolizidine skeleton in satisfactory high and reproducible yields by using allylic compound having an acetoxyl group as a leaving group. These results must be available for syntheses of various functional indolizidine alkaloids.

A New Synthetic Method for an Indolizidine Skeleton by C-N Bond Formation via a .PI.-Allylpalladium Complex