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Photoisomerisation of (2E)- and (2Z)-3-methyl-1-phenylbutane-1,2-dione 2-oxime (MPBDO) in several solvents was studied. With increasing dielectric constants of solvents, kinetic constants of forward reactions (E-form--&gt;Z-form) did not change appreciably but those of reverse reactions (Z-form--&gt;E-form) decreased. The positive correlation was found between equilibrium constants of photoisomerisation and dielectric constants of solvents.

Solvent Effect on Photoisomerisation of 3-Methyl-1-phenylbutane-1,2-dione 2-Oxime.