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The structure including the absolute configuration of a new glucoalkaloid, 3,4-dehydro-5(S)-5-carboxystrictosidine, isolated from Peruvian Uña de Gato (Cat's Claw, original plant: Uncaria tomentosa), was confirmed by synthesis starting from secologanin and L-tryptophan.

chemical and pharmaceutical bulletin/chemical and pharmaceutical bulletin

Synthesis and Absolute Configuration of a New 3,4-Dihydro-.BETA.-carboline-Type Alkaloid, 3,4-Dehydro-5(S)-5-carboxystrictosidine, Isolated from Peruvian Una de Gato (Uncaria tomentosa).