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A new pyrrolizidine alkaloid, broussonetine N, was isolated from the branches of Broussonetia kazinoki SIEB. (Moraceae).Broussonetine N was formulated as (1R, 2R, 3R, 5S, 8R)-1, 2-dihydroxy-3-hydroxymethyl-5[(1R)-1, 10-dihydroxy-6-oxo-decyl]pyrrolizidine (1) by spectoroscopic and chemical methods. 1 inhibited β-glucosidase, β-galactosidase, and β-mannosidase. Absolute stereostructures of broussonetines A (2) and B (3) as well as that of 1 were also determined by a new version of Mosher's method.

chemical and pharmaceutical bulletin/chemical and pharmaceutical bulletin

A New Pyrrolizidine Alkaloid, Broussonetine N, as an Inhibitor of Glycosidase, from Broussonetia kazinoki SIEB. and Absolute Stereostructures of Broussonetines A and B.