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Five new secospatane diterpenoids, secospatacetal A, B, C, D, and E have been isolated from the brown alga Dilophus okamurai DAWSON, and their structures as well as absolute configurations have been elucidated by means of NMR spectroscopy and chemical transformations Also, the structure of a known spatane diterpene has been revised.

Structures and Absolute Stereochemistry of Five New Secospatanes and a Spatane Isolated from the Brown Alga Dilophus okamurai Dawson.