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7-Carboxymethylmonensin (3), 7-aminomonensin (4), and 7-oxomonensin (5) were synthesized via protected 7-oxomonensin (2), which is expected to be a useful intermediate for the preparation of various monensin derivatives. intermediate for the preparation of various monensin derivatives. Compounds 3-5 exhibited smaller ion transport activity than monensin (1).

chemical and pharmaceutical bulletin/chemical and pharmaceutical bulletin

Studies on Chemical Modification of Monensin. VI. Preparation of C-7 Modified Monensins via Protected 7-Oxomonensin and Evaluation of Their Ion Transport Activity.