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The copper ions in the imidazole-clusters of histidine-oligopeptide, His(His)nGly (n = 18) and N-acetyl-His(His)nGly(n = 8 and 18), showed the d-d transition bands at 520 nm and 630 nm and oxidase-like activities. Those with the d-d bands at 480 nm and 550 nm did not have the activity.

chemical and pharmaceutical bulletin/chemical and pharmaceutical bulletin

Catalytic Activities and Coordination Environments of the Copper Ions in the Imidazole Clusters of Histidine-Peptides, His(His)nGly and N-Acetyl-His(His)nGly (n=3, 8, and 18).