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Diels-Alder reaction of methyl-substituted 1, 3-butadienes (1) with 1, 2-dibromoethylene gave dibromomethylcyclo-hexenes (2), which were subjected to epoxidation, followed by dehydrobromination of the resultant dibromo oxides (3) to afford 3-methylbenzene oxide (4a) and 1-methylbenzene oxide (4b). However, 4-methylbenzene oxide (4c) could not be obtained in this way

chemical and pharmaceutical bulletin/chemical and pharmaceutical bulletin

Facile Synthesis of 3-Methylbenzene Oxide and 1-Methylbenzene Oxide, and 1H-NMR Data for Diels-Alder Adducts of Three Methylbenzene Oxides with 4-Phenyl-1,2,4-triazoline-3,5-dione.