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Dynorphin A derivatives containing S-(3-nitro-2-pyridinesulfenyl)-cysteine(Cys(Npys)) were designed and synthesized for affinity labeling of kappa opioid receptors. Derivatives with Cys(Npys) residue at the 8 position were highly potent and specific to kappa receptors and bound to receptors through disulfide bond formation.

Design and Synthesis of Highly Potent and Specific Dynorphin Derivatives for Affinity Labeling of .KAPPA. Opioid Receptors.