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New compounds designated talaroderxines A (1) and B (2) were isolated from a new heterothallic ascomycetous fungus, Talaromyces derxii, cultivated on rice. The structures of 1a and 1b were elucidated by means of spectroscopic examination and chemical reactions. Talaroderxines A (1a) and B (1b) are atropisomers of a 6,6'-binaphtho-alpha-pyrone derivative, and have strong antibacterial activity against Bacillus subtilis.

chemical and pharmaceutical bulletin/chemical and pharmaceutical bulletin

Studies on Fungal Products. Part XXXVI. Isolation and Structures of Antibacterial Binaphtho-.ALPHA.-pyrones, Talaroderxines A and B, from Talaromyces derxii.