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2',3'-Dihydro-5'-formylgriseofulvin (3), oxymetholone (5), and 3 beta-acetoxy-16-acetoxymethylene-5-androsten-17-one (9) were used as the substrates of a cell-free system from Streptomyces cinereocrocatus NRRL 3443. The results indicated that S. cinereocrocatus contains enzymatic activities which reduce the above three alpha-hydroxymethylene-ketones to the corresponding alpha-hydroxymethyl-ketones.

chemical and pharmaceutical bulletin/chemical and pharmaceutical bulletin

The hydrogenation of .ALPHA.-hydroxymethylene-ketone derivatives to .ALPHA.-hydroxymethyl-ketone derivatives with a cell-free system of Streptomyces cinereocrocatus.