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A simple synthetic metho which can provide 3, 4, 5, 6-tetrahydro-1H-azepinol[5, 4, 3-cd]indole derivatives having a carbon side chain at any desired position of the nucleus was developed. The method was applied to the preparation of 4- and 5-alkyl-3, 4, 5, 6-tetrahydro-1H-azepino[5, 4, 3-cd]indoles

The chemistry of indoles. XLIV. Synthetic study directed toward 3,4,5,6-tetrahydro-1H-azepino[5,4,3-cd]indoles.