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Nine cembrane-type diterpenes were isolated from the lipid extract of the soft coral, Sinularia mayi. Of these, seven α-methylene-γ-lactone derivatives (1-7) had been previously isolated from various soft corals. The structures of the two new cembrane diols, sinulariol A (8a) and sinulariol B (9), were determined by means of spectroscopic analyses, and compound 9 was chemically correlated with nephthenol (11) whose absolute configuration is known. Compounds 8a and 9 are plausible precursors to the cembrane lactones found in various soft corals.

Marine terpenes and terpenoids. III. Isolation and structures of two cembrane diols from the soft coral Sinularia mayi.