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Highly ordered and three-dimensionally interconnected nanoporous materials, constructed with a nanothick wall of LiMPO4 (M = Fe, Mn) and a carbon (C) nanocomposite, were successfully synthesized by a colloidal crystal-template process. It was demonstrated for the first time that the ordered nanoporous composites show excellent rate capability not only for LiFePO4 but also for LiMnPO4

3D-ordered Nanoporous LiMPO4 (M = Fe, Mn)–Carbon Composites with Excellent Charging–Discharging Rate-capability