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A direct palladium-catalyzed highly regioselective C-3 arylation of imidazo[1,5- a ]pyridine with aryl bromides has been developed. This reaction is quite general with respect to the aryl or hetaryl bromide.

Palladium-catalyzed Highly Regioselective C-3 Arylation of Imidazo[1,5-a]pyridine