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Pd(II)-catalyzed cross-coupling of ortho -C-H bonds in benzoic acid and phenylacetic acid amides with alkyl-, aryl- and vinyl-boron reagents have been achieved via Pd(II)/Pd(0) catalysis, demonstrating the unprecedented versatility of C-H activation reactions.

Pd(II)-catalyzed Cross-coupling of C(sp2)–H Bonds and Alkyl–, Aryl–, and Vinyl–Boron Reagents via Pd(II)/Pd(0) Catalysis

Pd(II)-catalyzed Cross-coupling of C(sp²)–H Bonds and Alkyl–, Aryl–, and Vinyl–Boron Reagents via Pd(II)/Pd(0) Catalysis