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Atomic clusters were identified in the ground state of the non-equilibrium Ta phase (Frank-Kasper σ-structure type) at 15, 120 and 293 K. The evolution of the clusters with temperature leads to two phase transformations at 65 and 150 K which are related to the electrical and magnetic properties. The magnetic phase transition at 65 K is associated with the magnetic symmetry group transformation P4'2/mn'm ( 65 K). It is shown that β-U is also a two-component composite containing similar clusters. The nature of the stabilisation of β-Ta at the cathode is discussed.

Atomic clusters and phase transitions in the metastable β-Ta phase between 4.2 and 293 K