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Using grand-canonical Monte Carlo simulations we investigate the impact ofcharged walls on the crystallization properties of charged colloidalsuspensions confined between these walls. The investigations are based on aneffective model focussing on the colloids alone. Our results demonstrate thatthe fluid-wall interaction stemming from charged walls has a crucial impact onthe fluid's high-density behavior as compared to the case of uncharged walls.In particular, based on an analysis of in-plane bond order parameters we findsurface-charge-induced freezing and melting transitions.

Surface-charge-induced freezing of colloidal suspensions