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We synthesized single-phase CoS 2  on a large scale by adding graphene oxide of sufficient quantity via the hydrothermal method using cobalt acetate and thioacetamide as precursors; this produced the hybrid of CoS 2  with reduced graphene oxide which exhibited high electrocatalytic activity in the hydrogen evolution reaction.   Electronic supplementary material  The online version of this article (doi:10.1186/s40580-016-0066-x) contains supplementary material, which is available to authorized users.

Selective synthesis of pure cobalt disulfide on reduced graphene oxide sheets and its high electrocatalytic activity for hydrogen evolution reaction