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The potential use of colorimetric sensors has received significant attention due to its feasibility for use in various applications. After reacting with a sample, the image of the colorimetric sensor can be captured and converted into digital data using several different color models. The analytical data can then be processed with various chemometric methods. This research study investigated the predictive performance of calibration models established using color models commonly used in analytical chemistry including RGB, CMYK, HSV and CIELAB. A total of eight commercially available colorimetric sensors were used to determine the presence of manganese (Mn 2+ ), copper (Cu 2+ ), iron (Fe 2+ /Fe 3+ ), nitrate (NO 3 – ), phosphate (PO 4 3– ), sulfate (SO 4 2– ), as well as total hardness and pH values. As external validation tests, real water samples collected in Chiang Mai, Thailand were used. Based on the resulting data obtained using the synthetic test samples, the color that was most similar to the appearing color of the chemical sensor could offer satisfactory results. However, it was not always the case especially when the strips composed of multiple colorimetric sensors or sensor array were used. When tested with external validation, the predictive performance could be improved using appropriate data preprocessing and, in this research study, a normalization method was recommended to guarantee the accuracy of the calibration models.

journal of analytical science and technology

Investigation into the predictive performance of colorimetric sensor strips using RGB, CMYK, HSV, and CIELAB coupled with various data preprocessing methods: a case study on an analysis of water quality parameters