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Pulsed amperometric detection is a relatively new method for detection of ions and especially non-electrolytes such as carbohydrates in aqueous solutions. Pulsed amperometric detection relies on a redox reaction while electrochemical impedance simply measures the real and capacitive resistant of the solution.  There is a correlation between the real impedance of a solution and the ionic strength of the solution.

Determining detection limits of aqueous anions using electrochemical impedance spectroscopy