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A facile and efficient palladium-catalyzed borylation of aryl (pseudo)halides at room temperature has been developed. Arylboronic esters were expeditiously assembled in good yields and with a broad substrate scope and good functional group compatibility. This approach has been successfully applied to the one-pot two-step borylation/Suzuki–Miyaura cross-coupling reaction, providing a concise access to biaryl compounds from readily available aryl halides. Furthermore, a parallel synthesis of biaryl analogs is accomplished at room temperature using the strategy, which enhances the practical usefulness of this method.   Electronic supplementary material  The online version of this article (10.1186/s13065-018-0510-6) contains supplementary material, which is available to authorized users.

Palladium-catalyzed borylation of aryl (pseudo)halides and its applications in biaryl synthesis