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Ti-doped nano MgAl 2 O 4  for white emission was synthesized by combustion method. Extrinsic Schottky defects, Al vacancies and Ti 4+  dopant in Al sites, which are considered to be responsible for bluish-white emission, were observed by STEM on the surface of Ti-doped nano MgAl 2 O 4  powder. The stabilities of the Schottky defect associates, (Ti Al   · –V Al ′′′)′′, were demonstrated by DFT calculation. The emission behavior was interpreted with these results.

Defects on the Surface of Ti-Doped MgAl2O4 Nanophosphor