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Background  Trichloroethene and tetrachloroethene are the most common pollutants in groundwater and two of the priority pollutants listed by the U.S. Environmental Protection Agency. In previous studies on TCE and PCE photolysis and photochemical degradation, concentration ranges exceeding environmental levels by far with millimolar concentrations of TCE and PCE have been used, and it is not clear if the obtained results can be used to explain the degradation of these contaminants at more realistic environmental concentration levels.    Methods  Experiments with micromolar concentrations of TCE and PCE in aqueous solution using direct photolysis and UV/H 2 O 2  have been conducted and product formation as well as transformation efficiency have been investigated. SPME/GC/MS, HPLC/UV and ion chromatography with conductivity detection have been used to determine intermediates of degradation.    Results  The results showed that chloride was a major end product in both TCE and PCE photodegradation. Several intermediates such as formic acid, dichloroacetic acid, dichloroacetaldehyede, chloroform, formaldehyde and glyoxylic acid were formed during both, UV and UV/H 2 O 2  treatment of TCE. However chloroacetaldehyde and chloroacetic acid were only detected during direct UV photolysis of TCE and oxalic acid was only formed during the UV/H 2 O 2  process. For PCE photodegradation, formic acid, di- and trichloroacetic acids were detected in both UV and UV/H 2 O 2  systems, but formaldehyde and glyoxylic acid were only detected during direct UV photolysis.    Conclusions  For water treatment UV/H 2 O 2  seems to be favorable over direct UV photolysis because of its higher degradation efficiency and lower risk for the formation of harmful intermediates.

Transformation efficiency and formation of transformation products during photochemical degradation of TCE and PCE at micromolar concentrations