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A new unique steroidal glycoside, granulatoside C (1), was isolated from the ethanol extract of the starfish Choriaster granulatus. The structure of 1 was elucidated by extensive NMR and ESI-MS techniques as (20 R)-16,21- O-di-(P-D-fucopyranosyl)-24-methyl-cholesta-5,24(28)-diene-3p,7a,16a,21-tetraol (1). This glycoside is unusual one, because combines some characteristic structural peculiarities of steroids from several different phyla of marine invertebrates, it has a range of structural features that not previously found in starfish polyhydroxysteroidal glycosides, such as Δ 5 -3β,7α,16α-trihydroxysteroidal nucleus, Δ 24(28) -21-hydroxy-24-methyl-cholestane side chain and 16,21-diglycosylation by D-fucopyranosyl residues, but also characteristic of sponges, ophiuroids and soft corals, respectively.

natural product communications

A New Steroidal Glycoside Granulatoside C from the Starfish <i>Choriaster granulatus</i>, Unexpectedly Combining Structural Features of Polar Steroids from Several Different Marine Invertebrate Phyla

A New Steroidal Glycoside Granulatoside C from the Starfish Choriaster granulatus, Unexpectedly Combining Structural Features of Polar Steroids from Several Different Marine Invertebrate Phyla