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Seven cyclic lipopeptide biosurfactants (1–7) were isolated for the first time from the fermentation broth of endophytic Bacillus clausii DTM1 and were identified as anteisoC 13 [Val7] surfactin-(L-Glu)-O-methyl-ester (1), anteisoC 12 [Val7] surfactin (2), anteisoC 15 [Val7] surfactin (3), isoC 14 [Leu7] surfactin (4), anteisoC 12 [Leu7] surfactin (5), nC 13 [Leu7] surfactin (6), and anteisoC 14 [Leu7] surfactin-(L-Glu)-O-methyl-ester (7); 1 has not been isolated before as a natural product from any source. Plate-based herbicide and insecticide bioassays showed that all compounds exhibited interesting insecticidal and herbicidal activities.

Cyclic Lipopeptides with Herbicidal and Insecticidal Activities Produced by Bacillus clausii DTM1