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In the course of a screening program, we have isolated the new natural product, 5,7-dihydroxy-5,6,7,8-tetrahydroazocin-2(1H)-one (1), from the staurosporine producing marine-derived Streptomyces sp. strain QD518. Here we report the isolation and structure elucidation of 1 and the artifacts 3 and 4 resulting from 1 by acid catalyzed intra- and inter-molecular reactions.

5,7-Dihydroxy-5,6,7,8-tetrahydro-1H-azocin-2-one from a Marine-derived Streptomyces sp.