English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The work aims to study the chemical desorption process of CO2 in an aqueous solution of 2amino-2-methyl-1-propanol (AMP) and piperazine (PZ) carbonated blend. An Aspen Hysys® simulation was carried out to evaluate the CO2 capture process, which allowed to reduce CO2 emissions by 78.9 % for the same butane combustion process producing the same energy. The desorption process was performed on a wet wall column with 49 cm long and 2.2 cm diameter film promoter. The process was online monitored by infrared spectroscopy integrated with a multivariate calibration, which allowed the quantification of free AMP and PZ, CO2 in its all chemical forms, PZ monoand dicarbamate, and bicarbonate. The desorption tests were performed at atmospheric pressure (0.93 atm) and at temperatures of 50, 60 and 70 ° C, with a liquid flow rate of 3.478 mL∙s. The dry air flow varied between the experiments from 87.5 to 120 mL∙s. For each temperature, four aqueous solutions of different concentrations of AMP and PZ were evaluated, with %w/w de AMP/%w/w PZ: 30/0, 25/5, 20/10 and 0/15. The individual transport coefficient in the liquid phase was influenced by the concentration of PZ in the mixture with AMP, the higher the PZ concentration, the higher the PZ concentration. This coefficient decreases with increasing loading (α) of non-liquid CO2 (mole of CO2 per mole of amine in the initial solution). A temperature did not show a significant influence on the values of the individual coefficient of the liquid phase. The liquid film mass transfer coefficient encountered were in the range of 3.12×10 to 1.32×10 mol‧Pa‧m‧s, for loadings varying from 0.18 to 0.9 and solutions of AMP (0 – 30 wt%) and of PZ (0 – 15 wt%).

Estudo do processo de dessorção de CO2 da mistura 2-amino-2-metil-1-propanol e piperazina carbonatada.