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The photochemical behaviour of monohalogeno-phenols and -anilines is highly dependent onthe position of the halogen on the ring, but most often it is not significantly influenced by the nature ofthe halogen (Cl, Br, F). Photohydrolysis is the main reaction observed with 3-halogenated and it is almostspecific. With 2-halogenated, photohydrolysis and photocontraction of the ring compete, the latter beingvery efficient with 2-halogeno-phenolates

Phototransformation of halogenoaromatic derivatives in aqueous solution