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The reversible photochemistry of the α-subunit of phycoerythrocyanin (α-PEC) has been measuredby low temperature absorption and circular dichroism in the range of 125K to 295 K. Below 185 K, thephotochemistry is nearly silent; above 205 K, the photochemistry increases gradually without an indicationof intermediates, and between 185 to 205K spectral changes in absorption and circular dichroism indicatean intermediate and/or changes in the interaction(s) between the chromophore and its environment

international journal of photoenergy

Intermediates of reversible photochemistry of phycoerythrocyanin α from Mastigocladus laminosus probed by low temperature absorption and circular dichroism spectroscopy