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Two different commercial photocatalysts, Degussa P25 and Hombikat UV 100, were used to degrade1,4-dioxane photocatalytically in an annular slurry photoreactor. The optimum photocatalyst loadingfor Degussa P25 was found to be 1.5 g L-1 while for Hombikat UV 100 was between 3.0−4.0 g L-1. The photoactivityof Degussa P25 is higher than that of Hombikat at lower photocatalyst loadings whereas it is lowerat higher photocatalyst loadings. This was found both experimentally and also by mathematical modeling ofthe radiation within the photoreactor zone. The photoactivity of UV 100 titanium dioxide was found to betwice that of Degussa P25 at optimum loadings

Comparison of the photoactivities of two commercial titanium dioxide powders in the degradation of 1,4-dioxane