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Photolysis of phenol and p-chlorophenol exposed to KrCl- and Nd-YAG laser light is studiedby electron spectroscopy and fluorescence and quantum chemical techniques. The decrease of the quantumyield of phenol fluorescence with increase in the excitation energy is not related to dynamic changes inthe intramolecular photophysical processes; rather this is a result of increased photoreaction efficiency.Chlorine substitution for para-state of phenol is shown to strengthen the OH-bond in excitation into thelong wavelength absorption band

The fluorescence analysis of laser photolysis of phenols in water