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Photocatalytic degradation of tetrahydrofuran, 1,4-dioxane, and their mixture in a slurry photoreactorwas studied. Using both GC/MS and ion chromatography (IC) methods, possible intermediates weredetected and the reaction mechanism pathways for both compounds were proposed. Kinetic models weredeveloped and the kinetic parameters were estimated using a statistical method of non-linear parameter estimationin which all experimental data were utilized. It was shown that tetrahydrofuran was disappeared viadirect oxidation as well as hydroxyl radical attack. A modified Langmuir-Hinshelwood described the degradationbehavior of tetrahydrofuran and the binary system. 1,4-Dioxane obeyed a simple Langmuir-Hinshelwoodkinetic form in the single compound system

Photocatalytic degradation of aqueous tetrahydrofuran, 1,4-dioxane, and their mixture with TiO2

Photocatalytic degradation of aqueous tetrahydrofuran, 1,4-dioxane, and their mixture with TiO₂