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Zinc bacteriochlorophyll-d derivatives possessing a polymerizable moiety at the  17-propionate were prepared as model compounds of natural occurring chlorophylls  in the main peripheral antennas of green photosynthetic bacteria (chlorosomes).  The synthetic compounds self-aggregated in nonpolar organic solvents as well as  in the solid state to give large oligomers similar to chlorosomal J-aggregates.  Such introduction of the polymerizable groups in the ester did not suppress the ability of  self-aggregation

international journal of photoenergy

Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteria